Let's talk a little about thermocouple wire alloys:
There are about 6 principal thermocouple pairs in common use:
Where,
Each of these alloy combinations makes a dandy thermocouple, but each also has unique characteristics relative to soldering with conventional tin/lead solders, or welding.
Basically any alloy that has significant quantities of Chromium, Platinum, Rhodium, or Aluminum will be difficult to solder.
Copper solders nicely, iron solders nicely, nickel pretty well..,
-Chuck Harris